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Transition Metal Catalysts / Orgabinetallic Compounds

Metallocene Compouns

Titanocene dichloride


FORMURA SUBSTANCETitanocene dichloride
FORMURA[(C5H5)2TiCl2]
CAS No 1271-19-8
APPLICATIONSCatalysts(Polymerization/Hydrogenation/Organic Synthesis),
Electronics Materials, Curing Agent
MSDS

Titanocene Dichloride Technical Data



Trial Product Zirconocene dichloride
FORMURA SUBSTANCEZirconocene dichloride
FORMURA[(C5H5)2ZrCl2]
CAS No1291-32-3
APPLICATIONSCatalysts(Polymerization/Organic Synthesis)              
Electronics Materials, Stabilizer
MSDS

Zirconocene Dichloride Technical Data

Application to organic syntheses of Zirconocene dichloride

Negishi reagent [Cp2ZrBu2] derived from zirconocene dichloride using was used for high-stereoselective and regioselective coupling reaction or cyclization. For example, multisubstituted pentacene derivatives having high carrier mobility were synthesized by Negishi reagent.

Synthesis of multisubstituted acenes

Takahashi,T.;Kitamura,M.;Shen,B.;Nakajima,K.J.Am.Chem.Soc.2000,122,12876-12877





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