천이 금속 촉매/금속 합성물

Metallocene

Titanocene dichloride

FORMURA SUBSTANCETitanocene dichloride
FORMULA[(C5H5)2TiCl2]
CAS No 1271-19-8
APPLICATIONSCatalysts(Polymerization/Hydrogenation/Organic Synthesis),
Electronics Materials, Curing Agent
MSDS

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Trial Product Zirconocene dichloride

FORMURA SUBSTANCEZirconocene dichloride
FORMULA[(C5H5)2ZrCl2]
CAS No1291-32-3
APPLICATIONS Catalysts(Polymerization/Organic Synthesis),Electronics Materials, Stabilizer
MSDS

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Application to organic syntheses of Zirconocene dichloride

Negishi reagent [Cp2ZrBu2] derived from zirconocene dichloride using was used for high-stereoselective and regioselective coupling reaction or cyclization. For example, multisubstituted pentacene derivatives having high carrier mobility were synthesized by Negishi reagent.

Synthesis of multisubstituted acenes


Takahashi,T.;Kitamura,M.;Shen,B.;Nakajima,K.J.Am.Chem.Soc.2000,122,12876-12877

Trial Product

SUBSTANCE Zirconocene Chloride Hydride(trivial name: Schwartz Reagent)
FORMULA[(C5H5)2ZrHCl]
CAS No 32342-97-5
APPLICATIONSOrganic Synthesis

PDF Download Schwartz Reagent Technical Data